Lab Home | Phone | Search
Center for Nonlinear Studies  Center for Nonlinear Studies
 Home 
 People 
 Current 
 Executive Committee 
 Postdocs 
 Visitors 
 Students 
 Research 
 Publications 
 Conferences 
 Workshops 
 Sponsorship 
 Talks 
 Seminars 
 Postdoc Seminars Archive 
 Quantum Lunch 
 Quantum Lunch Archive 
 P/T Colloquia 
 Archive 
 Ulam Scholar 
 
 Postdoc Nominations 
 Student Requests 
 Student Program 
 Visitor Requests 
 Description 
 Past Visitors 
 Services 
 General 
 
 History of CNLS 
 
 Maps, Directions 
 CNLS Office 
 T-Division 
 LANL 
 
Tuesday, August 29, 2023
1:00 PM - 2:00 PM
CNLS Conference Room (TA-3, Bldg 1690)

Seminar

Path integral formulation of stochastic processes: non-equilibrium reaction pathways, hyperdynamics, and enhanced sampling

Steve Fitzgerald
Department of Applied Mathematics, University of Leeds, UK

Traditionally, stochastic processes are modelled one of two ways: a continuum Fokker-Planck approach, where a PDE is solved to determine the time evolution of the probability density, or a Langevin approach, where the SDE describing the system is sampled, and multiple simulations are used to collect statistics. There is also a third way: the functional or path integral. Originally developed by Wiener in the 1920s to model Brownian motion, path integrals were famously applied to quantum mechanics by Feynman in the 1950s. However, they also have much to offer classical stochastic processes (and statistical physics). In this talk I will introduce the formalism at a physicist's level of rigour, and focus on determining the dominant contribution to the path integral when the noise is weak. There exists a remarkable correspondence between the most-probable stochastic paths and Hamiltonian dynamics in an effective potential [1,2]. I will then discuss some applications, mainly in the general area of rare events. The first concerns reaction pathways conditioned on finite time [2], and demonstrates that the most probable pathway at a finite time may be very different from the usual minimum energy path used to calculate the average reaction rate. Secondly, I will review the path integral hyperdynamics introduced by Chen and Horing in 2007 [3], and discuss its application to non-equilibrium processes [4]. Finally, if time permits, I will share some more speculative ideas on exploiting the path integral to accelerate the sampling of rare events.

Join by phone

+1-415-655-0002 US Toll

Access code: 2637 917 4437



Host: Danny Perez (T-1)